Circularly Polarized Luminescence Fundamentals Explained

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The second reaction cycle in NO synthesis includes O2 binding to ferrous NOS to form the Fe, IIO2 intermediate, followed by oxidation of NOHA to produce ferric enzyme, NO, citrulline, and water as products (Fig. 9) - Resources circularly polarized luminescence. As drawn in Fig - https://pblc.me/pub/3fc0b3e264b77b. 9, the response may also involve electron transfer from H4B to the Fe, IIO2 intermediate

l9 As displayed in Fig. 9, this could be because the H4B radical acts as an electron sink in a later point in the reaction, so as to enable NOS to, Fig. 9. A model for NORA oxidation by NOSoxy in the single turnover reaction. Oxygen binds to the ferrous protein to form the Fe, IIO2 types, which upon receiving an electron from H4B forms a putative hemeperoxo intermediate that reacts with NOHA.